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Dendrite suppression with zirconium (IV) based metal-organic frameworks modified glass microfiber separator for ultralong-life rechargeable zinc-ion batteries
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Document Title
Dendrite suppression with zirconium (IV) based metal-organic frameworks modified glass microfiber separator for ultralong-life rechargeable zinc-ion batteries
Author
Maeboonruan N, Lohitkarn J, Poochai C, Lomas T, Wisitsoraat A, Kheawhom S, Siwamogsatham S, Tuantranont A, Sriprachuabwong C
Name from Authors Collection
Scopus Author ID
8532633300
Affiliations
National Science & Technology Development Agency - Thailand; Chulalongkorn University
Type
Article
Source Title
JOURNAL OF SCIENCE-ADVANCED MATERIALS AND DEVICES
ISSN
2468-2284
Year
2022
Volume
7
Issue
6
Open Access
gold
Publisher
VIETNAM NATL UNIV
DOI
10.1016/j.jsamd.2022.100467
Format
Abstract
Metal-organic frameworks (MOFs) are increasingly employed in designing an active material for various battery systems due to the variety of structures, morphology, and controllable composition at a molecular level. Moreover, their high porosity enables a facile electrolyte penetration and ion transportation. In this work, we focus on the performance and life cycle of aqueous rechargeable zinc-ion batteries (ZIBs) using zirconium (IV) based MOFs, including UiO-66 and MOF-808 modified glass microfiber separators. The results demonstrated that the symmetrical cell using MOF-808 modified separator extended a relatively stable voltage plateau of symmetric Zn battery over 350 h owing to improved uniformity of Zn ion flux during striping/plating processes. For the capacity retention at the current density of 1.0 A g(-1), the ZIBs using UiO-66@GFC and MOF-808@GFC exhibited higher specific capacities than that using the pristine separator. In addition, the ZIBs with MOF-808 modified separators could prolong the cycle life to as high as 8000 cycles because the modified separators could inhibit non-uniform dendritic zinc growth on a zinc anode surface according to scanning electron micrographs. Hence, the UiO-66 and MOF-808 modified glass microfibers as separators are promising materials for high-performance aqueous zinc-ion batteries with long-life cycles. (C) 2022 Vietnam National University, Hanoi. Published by Elsevier B.V.
Industrial Classification
Knowledge Taxonomy Level 1
Knowledge Taxonomy Level 2
Knowledge Taxonomy Level 3
Funding Sponsor
National Science and Technology Development Agency (NSTDA) : Development of cost-effective and high cyclability rechargeable zinc-ion battery [P1950722]; PMU C under the office of National Higher Education Science Research and Innovation Policy Council [P2051951]; Graphene and Printed Electronics for Dual-Use Applications Research Division (GPERD) , Thailand
License
CC-BY-NC-ND
Rights
Authors
Publication Source
WOS