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High voltage aqueous based energy storage with 揥ater-in-LiNO3� electrolyte
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Document Title
High voltage aqueous based energy storage with 揥ater-in-LiNO3� electrolyte
Author
Tulaphon P. Tantitumrongwut P. Ditkanaruxkul T. Bunpheng A. Tangthana-umrung K. Chomkhuntod P. Iamprasertkun P.
Affiliations
School of Bio-Chemical Engineering and Technology Sirindhorn International Institute of Technology Thammasat University Pathum Thani12120 Thailand; National Nanotechnology Center (NANOTEC) National Science and Technology Development Agency (NSTDA) Pathum Thani Khlong Luang 12120 Thailand
Type
Article
Source Title
Chemical Engineering Journal Advances
ISSN
26668211
Year
2023
Volume
16
Open Access
All Open Access Gold
Publisher
Elsevier B.V.
DOI
10.1016/j.ceja.2023.100553
Abstract
Electrochemical energy storage devices have gained considerable attention recently with 搘ater-in-salt� electrolytes emerging as a leading contender for use in lithium-ion batteries and supercapacitors. Herein the lithium nitrate (LiNO3) was then introduced as an inexpensive 搘ater-in-salt� electrolyte (explored from low to super-concentrated conditions) for fabricating the coin cell supercapacitors instead of conventional lithium bis(trifluoromethanesulfonyl)imide (LiTFSI). The transition of electrolyte properties from 搒alt-in-water� to 搘ater-in-salt� e.g. viscosity ionic conductivity density pH wettability and surface tension are demonstrated. Specifically the 20 m LiNO3 exhibits a significantly lower viscosity (4.99 ? 0.05 cP) that is approximately 6.4 times lower than the 21 m LiTFSI (32 cP). Moreover the LiNO3 also provides high ionic conductivity (100.6 ? 0.12 mS cm?1) which is 12.6 times higher than the LiTFSI (8 mS cm?1). The fabrication of the supercapacitor using these electrolytes in the coin cell level was then discussed highlighted on the electrode composition and current collector-which to the best of our knowledge. The use of highly concentrated LiNO3 in conjunction with an appropriate current collector and electrode composition represents an important step forward in the development of practical supercapacitors. The as-fabricated carbon-based supercapacitor using 20 m LiNO3 exhibits a broad electrochemical stability window range of up to 2.2 V with exceptional rate capability and remarkable cyclic stability. Thus this work will establish practical aspects of the LiNO3 as a 搘ater-in-salt� electrolyte instead of using high-cost LiTFSI. The successful implementation of these simple techniques provides a promising path toward commercializing next-generation energy storage devices. ? 2023 The Author(s)
Keyword
Current collectors | Electrolyte | LiNO3 | Supercapacitors | 揥ater-in-salt�
Industrial Classification
Knowledge Taxonomy Level 1
Knowledge Taxonomy Level 2
Knowledge Taxonomy Level 3
License
CC BY
Rights
Authors
Publication Source
WOS